Official Answer Key & Detailed Solution
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Correct Answer: Option (C) — Both of them give colour with iodine
Concept & Option Breakdown
Standard Reference Verified- Statement (a) is correct: Both starch and cellulose are natural biopolymers synthesized by plants.
- Statement (b) is correct: Both are high-molecular-weight polysaccharides made of long chains of repeating units.
- Statement (c) is incorrect: Starch forms a helical structure that traps iodine (triiodide ions) to give a characteristic deep blue-black color. Cellulose possesses a straight, uncoiled β-(1,4) glucan chain stabilized by hydrogen bonds and does not form this helical complex, thus giving no color with iodine solution.
- Statement (d) is correct: Both are glucose polymers (starch contains α-D-glucose, whereas cellulose contains β-D-glucose).
The iodine test is specific to the helical amylose in starch; cellulose's linear beta-linkages do not form a complex with iodine.
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